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[γ-氧化铝催化臭氧化去除2-甲基异冰片醇的机理探讨]

[Mechanism discussion of gamma-alumina catalyzed ozonation for 2-methylisoborneol removal].

作者信息

Chen Zhong-Lin, Qi Fei, Xu Bing-Bing, Shen Ji-Min, Ben Yue, Ye Miao-Miao

机构信息

School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China.

出版信息

Huan Jing Ke Xue. 2007 Mar;28(3):563-8.

Abstract

The efficiency and mechanism in degradation of 2-methylisoborneol (MIB) as taste and odor compound in drinking water were studied under the condition where gamma-alumina catalyzed ozonation. As a result, gamma-alumina can behave distinct activity in enhancing the efficiency of ozonation MIB. Tert-butyl alcohol had a remarkable restrain effect on removal efficiency of catalytic ozonation MIB by gamma-alumina. The surface charge status and surface hydroxyl groups status of gamma-alumina and pH values of the solution can be linked together. When the pH value of solution was near the pH(zpc) of gamma-Al2O3, there was a most observable activity in catalyzed ozonation process. R(ct), which denoted the relative concentration of hydroxyl radical (*OH), was much higher in catalyzed ozonation process than in ozonation process. This result further illuminated that gamma-Al2O3 can promote ozone decomposition to produce *OH. Finally, it was investigated that the effect of r(P/I) on catalyzed ozone decomposition and ozone decomposition.

摘要

研究了在γ-氧化铝催化臭氧化条件下,饮用水中异味化合物2-甲基异莰醇(MIB)的降解效率及机制。结果表明,γ-氧化铝在提高臭氧化MIB的效率方面表现出明显的活性。叔丁醇对γ-氧化铝催化臭氧化MIB的去除效率有显著的抑制作用。γ-氧化铝的表面电荷状态、表面羟基状态与溶液的pH值有关。当溶液的pH值接近γ-Al2O3的零电荷点(pH(zpc))时,催化臭氧化过程中的活性最为明显。表示羟基自由基(OH)相对浓度的R(ct)在催化臭氧化过程中比在臭氧化过程中高得多。这一结果进一步表明,γ-Al2O3能促进臭氧分解产生OH。最后,研究了r(P/I)对催化臭氧分解和臭氧分解的影响。

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