Einax Mario, Ziehm Sonja, Dieterich Wolfgang, Maass Philipp
Fachbereich Physik, Universität Konstanz, Konstanz, Germany.
Phys Rev Lett. 2007 Jul 6;99(1):016106. doi: 10.1103/PhysRevLett.99.016106.
We study the nucleation kinetics of binary alloys formed by codeposition of A and B atoms onto a planar substrate with fluxes F(alpha) (alpha=A, B). Based on a generalization of mean-field rate equations, we derive scaling relations for the dependence of the number density of stable islands on the ratios D(alpha)/F(alpha), where D(alpha) are the diffusion coefficients of two types of adatoms. Novel scaling laws are predicted for different situations of cluster stabilities with respect to their size and composition. The predictions are validated by kinetic Monte Carlo simulations and can be tested in experiments.
我们研究了通过将A和B原子以通量F(α)(α = A, B)共沉积到平面衬底上形成的二元合金的成核动力学。基于平均场速率方程的推广,我们推导了稳定岛数量密度对D(α)/F(α) 比值的依赖关系的标度关系,其中D(α) 是两种类型吸附原子的扩散系数。针对团簇相对于其尺寸和组成的不同稳定性情况,预测了新的标度律。这些预测通过动力学蒙特卡罗模拟得到验证,并可在实验中进行检验。