Besseling R, Weeks Eric R, Schofield A B, Poon W C K
Scottish Universities Physics Alliance (SUPA) and School of Physics, The University of Edinburgh, Kings Buildings, Mayfield Road, Edinburgh EH9 3JZ, United Kingdom.
Phys Rev Lett. 2007 Jul 13;99(2):028301. doi: 10.1103/PhysRevLett.99.028301. Epub 2007 Jul 9.
Using fast confocal microscopy we image the three-dimensional dynamics of particles in a yielded hard-sphere colloidal glass under steady shear. The structural relaxation, observed in regions with uniform shear, is nearly isotropic but is distinctly different from that of quiescent metastable colloidal fluids. The inverse relaxation time tau(alpha)(-1) and diffusion constant D, as functions of the local shear rate gamma*, show marked shear thinning with tau(alpha)(-1) proportional to D proportional to gamma*(0.8) over more than two decades in gamma*. In contrast, the global rheology of the system displays Herschel-Bulkley behavior. We discuss the possible role of large scale shear localization and other mechanisms in generating this difference.
我们使用快速共聚焦显微镜对处于稳定剪切状态下的屈服硬球胶体玻璃中粒子的三维动力学进行成像。在均匀剪切区域观察到的结构弛豫几乎是各向同性的,但与静态亚稳胶体流体的结构弛豫明显不同。作为局部剪切速率γ的函数,反向弛豫时间τ(α)(-1)和扩散常数D在γ的两个多十年里显示出明显的剪切变稀,τ(α)(-1)与D成正比,且D与γ*(0.8)成正比。相比之下,该系统的整体流变学表现出赫谢尔- Bulkley行为。我们讨论了大规模剪切局部化和其他机制在产生这种差异中可能发挥的作用。