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酸性品红染料在液体和固体介质中的非线性研究。

Nonlinear studies of acid fuchsin dye in liquid and solid media.

作者信息

Vinitha G, Ramalingam A

机构信息

Centre for Laser Technology, Department of Physics, Anna University, Chennai 600025, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2008 Apr;69(4):1160-4. doi: 10.1016/j.saa.2007.06.016. Epub 2007 Jun 22.

Abstract

Solid-state dye-doped polymers are attractive alternative to the conventional liquid dye solutions. In this paper, nonlinear properties of the dye Acid Fuchsin has been studied. The third-order nonlinear optical properties of Acid Fuchsin dye in 1-butanol and dye-doped polymer film were measured by the Z-scan technique using 532 nm diode pumped Nd:Yag laser. This material exhibits negative optical nonlinearity. The dye at 0.4 mM concentration exhibited nonlinear refractive coefficient (n(2)=-8.72 x 10(-8) and -10.308 x 10(-8) (cm(2)/W) in liquid and solid media, respectively), nonlinear absorption coefficient (beta=-7.69 x 10(-4) and -8.294 x 10(-4)cm/W in liquid and solid media, respectively) and susceptibility (chi(3)=4.33 x 10(-6) and 5.13 x 10(-5)esu in liquid and solid media, respectively). These results show that Acid Fuchsin dye has potential applications in nonlinear optics.

摘要

固态掺杂染料聚合物是传统液体染料溶液颇具吸引力的替代品。本文研究了酸性品红染料的非线性特性。使用532 nm二极管泵浦Nd:Yag激光器,通过Z扫描技术测量了酸性品红染料在正丁醇和掺杂染料聚合物薄膜中的三阶非线性光学特性。这种材料表现出负光学非线性。浓度为0.4 mM的染料在液体和固体介质中分别表现出非线性折射率(n(2)= -8.72×10(-8)和-10.308×10(-8) (cm(2)/W))、非线性吸收系数(β = -7.69×10(-4)和-8.294×10(-4)cm/W在液体和固体介质中)以及极化率(χ(3)= 4.33×10(-6)和5.13×10(-5)esu在液体和固体介质中)。这些结果表明酸性品红染料在非线性光学领域具有潜在应用。

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