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单壁碳纳米管的统计精确长度测量。

Statistically accurate length measurements of single-walled carbon nanotubes.

作者信息

Ziegler Kirk J, Rauwald Urs, Gu Zhenning, Liang Feng, Billups W E, Hauge Robert H, Smalley Richard E

机构信息

Department of Chemistry, Center for Nanoscale Science and Technology, Rice University, Houston, Texas 77005, USA.

出版信息

J Nanosci Nanotechnol. 2007 Aug;7(8):2917-21. doi: 10.1166/jnn.2007.608.

Abstract

The ability to accurately measure the length of nanotubes is important to understanding nanotube growth and cutting processes. To date, there have been few methods available to obtain a statistically significant length measurement of any nanotube sample due to difficulties in obtaining a complete suspension of individual nanotubes and the tedious nature of measuring 1000+ nanotubes. Here we describe a relatively simple method that functionalizes single-walled carbon nanotubes to achieve a high propensity of individual nanotubes in chloroform as high as 92%. This suspension can be dispersed on mica substrates for AFM analysis. Nanotube lengths and heights can be determined using the Nanotube Length Analysis module of SIMAGIS yielding an accurate measure of length and height distribution of a large population of the nanotube sample.

摘要

准确测量纳米管的长度对于理解纳米管的生长和切割过程至关重要。迄今为止,由于难以获得单个纳米管的完全悬浮液以及测量1000多个纳米管的繁琐性质,几乎没有可用的方法来获得任何纳米管样品具有统计学意义的长度测量值。在此,我们描述了一种相对简单的方法,该方法对单壁碳纳米管进行功能化处理,以使单个纳米管在氯仿中的高倾向性高达92%。这种悬浮液可以分散在云母基板上进行原子力显微镜(AFM)分析。可以使用SIMAGIS的纳米管长度分析模块确定纳米管的长度和高度,从而准确测量大量纳米管样品的长度和高度分布。

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