Gupta Puneet, Velazquez-Vargas Luis G, Valentine Charles, Fan Liang-Shih
Department of Chemical and Biomolecular Engineering, Ohio State University, Columbus, OH 43210, USA.
Rev Sci Instrum. 2007 Aug;78(8):085106. doi: 10.1063/1.2760746.
A moving bed scale reactor setup for studying complex gas-solid reactions has been designed in order to obtain kinetic data for scale-up purpose. In this bench scale reactor setup, gas and solid reactants can be contacted in a cocurrent and countercurrent manner at high temperatures. Gas and solid sampling can be performed through the reactor bed with their composition profiles determined at steady state. The reactor setup can be used to evaluate and corroborate model parameters accounting for intrinsic reaction rates in both simple and complex gas-solid reaction systems. The moving bed design allows experimentation over a variety of gas and solid compositions in a single experiment unlike differential bed reactors where the gas composition is usually fixed. The data obtained from the reactor can also be used for direct scale-up of designs for moving bed reactors.
为了获得用于放大目的的动力学数据,设计了一种用于研究复杂气固反应的移动床规模反应器装置。在这个实验室规模的反应器装置中,气体和固体反应物可以在高温下以并流和逆流方式接触。气体和固体采样可以通过反应器床层进行,其组成分布在稳态下确定。该反应器装置可用于评估和证实考虑简单和复杂气固反应系统中本征反应速率的模型参数。与通常固定气体组成的微分床反应器不同,移动床设计允许在单个实验中对各种气体和固体组成进行实验。从反应器获得的数据也可用于移动床反应器设计的直接放大。