Science. 1968 Jul 12;161(3837):160-3. doi: 10.1126/science.161.3837.160.
Sodium-aluminum silicate gels are found in surficial deposits as thick as 5 centimeters in the Magadi area of Kenya. Chemical data indicate they are formed by the interaction of hot alkaline springwaters (67 degrees to 82 degrees C; pH, about 9) with alkali trachyte flows and their detritus, rather than by direct precipitation. In the process, Na(2)O is added from and silica is released to the saline waters of the springs. Algal mats protect the gels from erosion and act as thermal insulators. The gels are probably yearly accumulates that are washed into the lakes during floods. Crystallization of these gels in the laboratory yields analcite; this fact suggests that some analcite beds in lacustrine deposits may have formed from gels. Textural evidence indicates that cherts of rocks of the Pleistocene chert series in the Magadi area may have formed from soft sodium silicate gels. Similar gels may have acted as substrates for the accumulation and preservation of prebiological organic matter during the Precambrian.
硅酸铝凝胶在肯尼亚马加迪地区的地表沉积物中厚达 5 厘米。化学数据表明,它们是由热碱性泉水(67 至 82°C;pH 值约为 9)与碱性流纹岩及其碎屑相互作用形成的,而不是直接沉淀形成的。在此过程中,Na2O 来自流纹岩,而二氧化硅则释放到泉水的盐水中。藻类垫保护凝胶免受侵蚀,并起到隔热的作用。凝胶可能是每年洪水期间冲入湖泊的堆积物。这些凝胶在实验室中的结晶生成方沸石;这一事实表明,湖泊沉积物中方沸石床可能是由凝胶形成的。结构证据表明,马加迪地区更新世燧石系列岩石中的燧石可能是由软的硅酸钠凝胶形成的。类似的凝胶可能在元古代时期充当了生物前有机物质积累和保存的基质。