Gómez-Segura Jordi, Veciana Jaume, Ruiz-Molina Daniel
Institut de Ciència de Materials de Barcelona (CSIC), Campus de la UAB, 08193 Bellaterra, Catalonia, Spain.
Chem Commun (Camb). 2007 Sep 28(36):3699-707. doi: 10.1039/b616352a. Epub 2007 Apr 20.
SMMs exhibit slow magnetization relaxation rates characteristic of nanodomain particles whose origin is however on individual molecules. For this reason, they have attracted much interest due to their potential applications in high-density information storage devices and quantum computing applications, where for instance, each molecule can be used as a magnetic bit of information. However, for this to become a reality, several basic studies such as their deposition on surfaces are still highly required. Here we will revise all the experimental approximations that have been so far reported for their addressing, nanostructuration and study on surfaces, from the use of stamps as templates to their anchorage to gold surface through the use of thiol-based ligands. It is also important to emphasize that the results and methodologies described along this review are applicable not only to SMMs but to any molecular material.
单分子磁体表现出纳米畴粒子特有的缓慢磁化弛豫速率,但其起源在于单个分子。因此,它们因其在高密度信息存储设备和量子计算应用中的潜在应用而备受关注,例如,在这些应用中,每个分子都可以用作信息的磁位。然而,要实现这一点,仍然非常需要进行一些基础研究,比如它们在表面的沉积。在这里,我们将回顾迄今为止报道的关于它们在表面的寻址、纳米结构化和研究的所有实验方法,从使用印章作为模板到通过使用硫醇基配体将它们固定在金表面。还需要强调的是,本综述中描述的结果和方法不仅适用于单分子磁体,也适用于任何分子材料。