Giannis A, Makripodis G, Simantiraki F, Somara M, Gidarakos E
Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, Politechnioupolis, Chania 73100, Greece.
Waste Manag. 2008;28(8):1346-54. doi: 10.1016/j.wasman.2007.06.024. Epub 2007 Sep 19.
Long-term biodegradation of MSW in an aerobic landfill bioreactor was monitored as a function of time during 510 days of operation. Operational characteristics such as air importation, temperature and leachate recirculation were monitored. The oxygen utilization rates and biodegradation of organic matter rates showed that aerobic biodegradation was feasible and appropriate to proceed in aerobic landfill bioreactor. Leachate analyses showed that the aerobic bioreactor could remove above 90% of chemical oxygen demand (COD) and close to 100% of biochemical oxygen demand (BOD5) from leachate. Ammonium (NH4+), nitrate (NO3-) and sulphate (SO4(2-)) concentrations of leachate samples were regularly measured. Results suggest that nitrification and denitrification occurred simultaneously, and the increase in nitrate did not reach the levels predicted stoichiometrically, suggesting that other processes were occurring. Leachate recirculation reduced the concentrations of heavy metals because of the effect of the high pH of the leachate, causing heavy metals to be retained by processes such as sorption on MSW, carbonate precipitation, and hydroxide precipitation. Furthermore, the compost derived from the aerobic biodegradation of the organic matter of MSW may be considered as soil improvement in the agricultural plant production. Bio-essays indicated that the ecotoxicity of leachate from the aerobic bioreactor was not toxic at the end of the experiment. Finally, after 510 days of degradation, waste settlement reached 26% mainly due to the compost of the organic matter.
在一个好氧垃圾填埋生物反应器中,对城市固体废弃物(MSW)的长期生物降解进行了为期510天的运行监测,并将其作为时间的函数。监测了诸如空气输入、温度和渗滤液回流等运行特性。氧气利用率和有机物生物降解率表明,好氧生物降解在好氧垃圾填埋生物反应器中是可行且合适的。渗滤液分析表明,好氧生物反应器可以去除渗滤液中90%以上的化学需氧量(COD)和接近100%的生化需氧量(BOD5)。定期测量渗滤液样品中的铵(NH4+)、硝酸盐(NO3-)和硫酸盐(SO4(2-))浓度。结果表明,硝化和反硝化同时发生,硝酸盐的增加未达到化学计量预测的水平,这表明还发生了其他过程。由于渗滤液高pH值的影响,渗滤液回流降低了重金属浓度,导致重金属通过诸如吸附在城市固体废弃物上、碳酸盐沉淀和氢氧化物沉淀等过程被保留。此外,城市固体废弃物有机物好氧生物降解产生的堆肥可被视为农业植物生产中的土壤改良剂。生物测定表明,在实验结束时,好氧生物反应器渗滤液的生态毒性无毒。最后,经过510天的降解,废物沉降率达到26%,主要是由于有机物的堆肥作用。