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一种新型消费后聚对苯二甲酸乙二酯(PET)回收概念的去污效率

Decontamination efficiency of a new post-consumer poly(ethylene terephthalate) (PET) recycling concept.

作者信息

Welle Frank

机构信息

Fraunhofer Institute for Process Engineering and Packaging (IVV), Giggenhauser Strasse 35, 85354 Freising, Germany.

出版信息

Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2008 Jan;25(1):123-31. doi: 10.1080/02652030701474227. Epub 2007 Sep 28.

Abstract

The aim of the study was to investigate and evaluate the cleaning efficiency of a new recycling concept for post-consumer poly(ethylene terephthalate) (PET). The so-called Flake To Resin (FTR) recycling process produces PET pellets or preforms from conventionally recycled PET flakes for the application in new PET packaging in direct food contact. The investigated process can be considered as 'super-clean' recycling process and was developed to introduce conventional recycled post-consumer (PCR) PET flakes up to an amount of 50% into the pellet and preform production. Within the study the cleaning efficiency of the investigated FTR process was determined by a challenge test. The experimental results obtained from three challenge tests with different input concentrations of the surrogates and different amounts of post-consumer PET flakes show that all applied surrogates are very efficiently removed by the investigated recycling process. The cleaning efficiencies for all surrogates are above 99.9%. In the final product of the process no surrogates could be determined above the detection limits (0.5 mg kg(-1)) even if the initial concentrations were in the percentage range. From a migrational point the final product, which are either PET pellets or preforms, was similar to virgin PET. Only the PET typical substances acetaldehyde and ethylene glycol had slightly higher concentrations than found in a conventional PET virgin sample used as reference. The generally accepted migration limit of 10 microg kg(-1) for the surrogates in the final products of the challenge tests is established for all kinds of foodstuffs.

摘要

该研究的目的是调查和评估一种用于消费后聚对苯二甲酸乙二酯(PET)的新型回收概念的清洁效率。所谓的“薄片到树脂”(FTR)回收工艺从传统回收的PET薄片中生产PET颗粒或瓶坯,用于直接接触食品的新型PET包装。所研究的工艺可被视为“超清洁”回收工艺,其开发目的是将高达50%的传统回收消费后(PCR)PET薄片引入颗粒和瓶坯生产中。在该研究中,通过挑战性试验确定了所研究的FTR工艺的清洁效率。从三次针对不同替代物输入浓度和不同量消费后PET薄片的挑战性试验中获得的实验结果表明,所研究的回收工艺能非常有效地去除所有应用的替代物。所有替代物的清洁效率均高于99.9%。即使初始浓度处于百分比范围,在该工艺的最终产品中也未检测到替代物超过检测限(0.5毫克/千克)。从迁移角度来看,最终产品(PET颗粒或瓶坯)与原生PET相似。只有PET典型物质乙醛和乙二醇的浓度略高于用作参考的传统原生PET样品中的浓度。针对挑战性试验最终产品中替代物普遍接受的迁移限值设定为10微克/千克,适用于所有食品。

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