具有双核、四核和六核簇的新型磺酸锰（II）膦酸盐。

Novel manganese(II) sulfonate-phosphonates with dinuclear, tetranuclear, and hexanuclear clusters.

作者信息

Du Zi-Yi, Prosvirin Andrey V, Mao Jiang-Gao

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR, China.

出版信息

Inorg Chem. 2007 Nov 12;46(23):9884-94. doi: 10.1021/ic701213g. Epub 2007 Oct 6.

DOI:10.1021/ic701213g

PMID:17918930

Abstract

Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S-Ph-PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II) sulfonate-phosphonates, namely, [Mn2(HL)2(phen)4]Mn2(HL)2(phen)4(H2O).6H2O (1), [Mn4(L)2(phen)8(H2O)2]ClO4.3H2O (2), [Mn(phen)(H2O)4]2[Mn4(L)4(phen)4].10H2O (3), [Mn6(L)4(phen)8(H2O)2].4H2O (4), [Mn6(L)4(phen)8(H2O)2].24H2O (5), and [Mn6(L)4(phen)6(H2O)4].5H2O (6). The structure of 1 contains two types of dinuclear manganese(II) clusters, and 2-3 exhibit two types of tetranuclear manganese(II) cluster units. 4-5 feature two different types of isolated hexanuclear manganese(II) clusters, whereas the hexanuclear manganese(II) clusters in 6 are bridged by sulfonate-phosphonate ligands into a 1D chain. Magnetic property measurements indicate that there exist weak antiferromagnetic interactions between magnetic centers in all six compounds.

摘要

锰（II）盐与间磺基苯膦酸（m-HO₃S-Ph-PO₃H₂，H₃L）和1,10-菲咯啉（phen）的水热反应生成了六种新型的磺酸根-膦酸根锰（II）配合物，即[Mn₂(HL)₂(phen)₄]Mn₂(HL)₂(phen)₄(H₂O).6H₂O（1）、[Mn₄(L)₂(phen)₈(H₂O)₂]ClO₄.3H₂O（2）、[Mn(phen)(H₂O)₄]₂[Mn₄(L)₄(phen)₄].10H₂O（3）、[Mn₆(L)₄(phen)₈(H₂O)₂].4H₂O（4）、[Mn₆(L)₄(phen)₈(H₂O)₂].24H₂O（5）和[Mn₆(L)₄(phen)₆(H₂O)₄].5H₂O（6）。1的结构包含两种双核锰（II）簇，2 - 3呈现两种四核锰（II）簇单元。4 - 5具有两种不同类型的孤立六核锰（II）簇，而6中的六核锰（II）簇通过磺酸根-膦酸根配体桥连形成一维链。磁性测量表明，所有六种化合物的磁性中心之间均存在弱反铁磁相互作用。