Valencia Ramón, Rodríguez-Fortea Antonio, Poblet Josep M
Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, 43007 Tarragona, Spain.
Chem Commun (Camb). 2007 Oct 28(40):4161-3. doi: 10.1039/b709548a. Epub 2007 Aug 6.
Structures are proposed for six endohedral metallofullerenes with large carbon cages (from C(92) to C(100)) on the basis of sizeable (LUMO-4)-(LUMO-3) gap and the formal transfer of six electrons to the cages.
基于可观的(最低未占分子轨道 - 4)-(最低未占分子轨道 - 3)能隙以及六个电子向碳笼的形式转移,提出了六个具有大碳笼(从C(92)到C(100))的内嵌金属富勒烯的结构。