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[上海某焦化厂PM10 - 梧桐树叶 - 土壤系统中多环芳烃(PAHs)的相关性]

[Correlation of polycyclic aromatic hydrocarbons (PAHs) in PM10- phoenix tree leaves-soil system of a coking & chemical factory in Shanghai].

作者信息

Cheng Jin-Ping, Zhao Wen-Chang, Xie Hai-Ying, Ma Ying-Ge, Zhang Jin, Ma Jing, Li Wei, Wang Wen-Hua

机构信息

School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.

出版信息

Huan Jing Ke Xue. 2007 Aug;28(8):1802-5.

Abstract

In order to study the distributions characteristics, sources and relationship of PAHs in PM10- phoenix tree leaves-soil system of a coking & chemical factory in Shanghai, the samples of PM10, phoenix tree leaves and soil around the factory were collected for a year. The concentration of PAHs were analyzed according to the USEPA method 8 000 series. The results showed that the average concentration of PAHs in PM10, phoenix tree leaves and soil were 101.11 ng/m3, 79.45 ng/g and 121.53 microg/g, respectively. Particulate phase (PM10) contained mainly carcinogenic and mutagenic PAHs, among which BaA, BghiP, Flu and BaP were found at significant concentrations. In phoenix tree leaves, Nap,Chy, BaP and BghiP presented a higher level of concentration. In soil, 3 and 4-ring PAHs presented a higher level. PAHs concentrations of phoenix tree leaves were very lower in May. Only Ace (0.16 ng/g) and Pyr (0.63 ng/g) were detected. In July and August the concentrations (39.19 ng/g and 150.94 ng/g, respectively) were uplifted significantly. It could be concluded PAHs was from petroleum and coal-fired compound source. There were very strong positive relationships of 16 PAHs level among phoenix tree leaves, soil and PM10 (p < 0.01).

摘要

为研究上海某焦化厂PM10-梧桐树叶-土壤系统中多环芳烃(PAHs)的分布特征、来源及相互关系,对该厂周边的PM10、梧桐树叶和土壤样本进行了为期一年的采集。按照美国环保署8000系列方法分析PAHs浓度。结果表明,PM10、梧桐树叶和土壤中PAHs的平均浓度分别为101.11 ng/m³、79.45 ng/g和121.53 μg/g。颗粒相(PM10)主要含有致癌和致突变的PAHs,其中苯并[a]蒽、苯并[ghi]芘、荧蒽和苯并[a]芘的浓度显著。梧桐树叶中,萘、屈、苯并[a]芘和苯并[ghi]芘的浓度较高。土壤中,三环和四环PAHs浓度较高。梧桐树叶中PAHs浓度在5月非常低,仅检测到苊(0.16 ng/g)和芘(0.63 ng/g)。7月和8月浓度显著升高(分别为39.19 ng/g和150.94 ng/g)。可以得出结论,PAHs来自石油和燃煤复合源。梧桐树叶、土壤和PM10中16种PAHs水平之间存在非常强的正相关关系(p < 0.01)。

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