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[碳酸钙在水溶性甲壳质中的晶体行为]

[The crystal behavior of calcium carbonate in water-soluable chitin].

作者信息

Song Rui, He Ling-Hao, Xie Qiao-Li, Yang Hao

机构信息

Department of Material and Chemical Engineering, Zhengzhou College of Light Industry, Zhengzhou 450002, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2007 Jul;27(7):1388-92.

Abstract

Based on the basic principles of biominerlization, the paper analyses calcium carbonate crystallization in waterable chitin solution under the control of chitin, using chitin as the matrix; and analyses the effect on crystals by varying temperature or pH of the system. The obtained calcium carbonate was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electronic microscopy(SEM) and X ray powder diffraction (XRD). As a result, it was found that crystals were different formed in purity water; and the obtained crystals are different in different concentration chitin solution. Calcium carbonate has effect on chitin during the calcium carbonate formation process, so there is the interaction between chitin and calcium carbonate.

摘要

基于生物矿化的基本原理,本文以几丁质为基质,分析了在几丁质控制下可水合几丁质溶液中碳酸钙的结晶情况;并通过改变体系温度或pH值来分析其对晶体的影响。采用傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和X射线粉末衍射(XRD)对所得碳酸钙进行表征。结果发现,在纯水中形成的晶体不同;在不同浓度的几丁质溶液中获得的晶体也不同。碳酸钙在形成过程中对几丁质有影响,因此几丁质与碳酸钙之间存在相互作用。

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