时域中的四阶相干拉曼光谱：在埋藏界面中的应用

Fourth-order coherent Raman spectroscopy in a time domain: applications to buried interfaces.

作者信息

Nomoto Tomonori, Onishi Hiroshi

机构信息

Department of Chemistry, Kobe University, Rokko-dai, Nada, Kobe, 657-8501, Japan.

出版信息

Phys Chem Chem Phys. 2007 Nov 7;9(41):5515-21. doi: 10.1039/b704566m. Epub 2007 Jul 5.

DOI:10.1039/b704566m

PMID:17957307

Abstract

A Raman-based, nonlinear optical spectroscopy is a promising method for observing vibrational modes localized at buried interfaces. The principles of Raman excitation and interface-selective detection of coherent vibrations are described. Applications to air-liquid, liquid-liquid, air-solid, liquid-solid, and solid-solid interfaces are reviewed.

摘要

基于拉曼的非线性光学光谱是一种用于观察埋入界面处局域振动模式的很有前景的方法。本文描述了拉曼激发原理以及相干振动的界面选择性检测原理。综述了其在气-液、液-液、气-固、液-固和固-固界面的应用。