Xia Hui-Li, Zhuang Hui-Sheng, Zhang Tao, Xiao Dong-Chang
College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China.
J Environ Sci (China). 2007;19(9):1141-5. doi: 10.1016/s1001-0742(07)60186-7.
The novel CuO-SnO2 nanocomposite oxide photocatalysts were prepared by simple co-precipitation method, and characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption-desorption measurement and UV-Vis diffuse reflectance spectroscopy. The photocatalytic activities of CuO-SnO2, evaluated using the photodegradation of Acid Blue 62 as a probe reaction under the irradiation of Xenon light, were also found to be related to the calcination temperature and the molar ratio of Cu to Sn. The maximum photocatalytic activity of the CuO-SnO2 photocatalyst was observed to be calcined at 500 degrees C for 3 h (the molar ratio of Cu to Sn was 1:1) due to the sample with good crystallization and high surface area. It also showed much higher photocatalytic activity in treatment dye wastewater under simulated sunlight irradiation compared to Degussa P25 TiO2.
采用简单的共沉淀法制备了新型CuO-SnO₂纳米复合氧化物光催化剂,并通过X射线衍射、透射电子显微镜、N₂吸附-脱附测量和紫外-可见漫反射光谱对其进行了表征。以酸性蓝62的光降解为探针反应,在氙灯光照下评估了CuO-SnO₂的光催化活性,发现其与煅烧温度和Cu与Sn的摩尔比有关。由于样品具有良好的结晶性和高比表面积,CuO-SnO₂光催化剂在500℃煅烧3 h(Cu与Sn的摩尔比为1:1)时观察到最大光催化活性。与Degussa P25 TiO₂相比,其在模拟太阳光照射下处理染料废水时也表现出更高的光催化活性。