Ha Na Young, Ohtsuka Youko, Jeong Soon Moon, Nishimura Suzushi, Suzaki Goroh, Takanishi Yoichi, Ishikawa Ken, Takezoe Hideo
Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan.
Nat Mater. 2008 Jan;7(1):43-7. doi: 10.1038/nmat2045. Epub 2007 Nov 11.
A cholesteric liquid crystal (CLC) is a self-assembled photonic crystal formed by rodlike molecules, including chiral molecules, that arrange themselves in a helical fashion. The CLC has a single photonic bandgap and an associated one-colour reflection band for circularly polarized light with the same handedness as the CLC helix (selective reflection). These optical characteristics, particularly the circular polarization of the reflected light, are attractive for applications in reflective colour displays without using a backlight, for use as polarizers or colour filters and for mirrorless lasing. Recently, we showed by numerical simulation that simultaneous multicolour reflection is possible by introducing fibonaccian phase defects. Here, we design and fabricate a CLC system consisting of thin isotropic films and of polymeric CLC films, and demonstrate experimentally simultaneous red, green and blue reflections (multiple photonic bandgaps) using the single-pitched polymeric CLC films. The experimental reflection spectra are well simulated by calculations. The presented system can extend applications of CLCs to a wide-band region and could give rise to new photonic devices, in which white or multicolour light is manipulated.
胆甾相液晶(CLC)是一种由棒状分子(包括手性分子)自组装形成的光子晶体,这些分子以螺旋方式排列。CLC具有单一光子带隙以及与具有和CLC螺旋相同手性的圆偏振光相关的单色反射带(选择性反射)。这些光学特性,特别是反射光的圆偏振特性,对于不使用背光源的反射式彩色显示器、用作偏振器或滤色器以及无镜激光应用具有吸引力。最近,我们通过数值模拟表明,引入斐波那契相位缺陷可以实现同时多色反射。在此,我们设计并制造了一个由各向同性薄膜和聚合物CLC薄膜组成的CLC系统,并使用单间距聚合物CLC薄膜通过实验证明了同时的红、绿、蓝反射(多个光子带隙)。实验反射光谱通过计算得到了很好的模拟。所展示的系统可以将CLC的应用扩展到宽带区域,并可能催生新的光子器件,其中白色或多色光得到操控。