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车辆沉降物对加纳普拉河口的影响(以铂族金属对海洋生态系统的影响为例)

The impact of vehicular fallout on the Pra estuary of Ghana (a case study of the impact of platinum group metals (PGMs) on the marine ecosystem).

作者信息

Essumang D K, Dodoo D K, Adokoh C K

机构信息

Environmental Research Group, Department of Chemistry, University of Cape Coast, Cape Coast, Ghana.

出版信息

Environ Monit Assess. 2008 Oct;145(1-3):283-94. doi: 10.1007/s10661-007-0037-0. Epub 2007 Dec 11.

Abstract

It is increasingly being recognised and environmental measurements have demonstrated that Platinum (Pt) (and potentially Rhodium (Rh) and Palladium (Pd)) is released with the ageing of catalytic converters. Platinum is a particular concern as it has a known mutagenic and toxic effect, even at exceedingly low concentrations, in urban air (affecting human health) and urban water (affecting ecosystem health). In the context given above and given the still keen lack of reliable experimental data on the levels of Pd, Pt and Rh in water and sediment, this study determined the concentration of such elements in water and sediment of the Pra estuary in the Western Region of Ghana where it is estimated that more than two thousand cars pass over the bridge under which the river flows to join the sea each day. Elevated concentrations of platinum (Pt), palladium (Pd) and Rhodium (Rh) were found to be associated with water and soils from areas of high traffic densities (Beposo) suggesting that vehicles also contribute heavy metals (PGMs) to the environment. The result showed elevated levels of these metals in river bank, waterbed and in the water. There is therefore the tendency of possible accumulation of these metals in plant and animals along these areas.

摘要

人们越来越认识到,环境测量表明,随着催化转化器的老化,铂(Pt)(以及可能的铑(Rh)和钯(Pd))会被释放出来。铂尤其令人担忧,因为即使在极低浓度下,它在城市空气中(影响人类健康)和城市水中(影响生态系统健康)都具有已知的诱变和毒性作用。在上述背景下,鉴于目前仍然极度缺乏关于水中和沉积物中钯、铂和铑含量的可靠实验数据,本研究测定了加纳西部地区普拉河口的水和沉积物中这些元素的浓度。据估计,每天有超过两千辆汽车驶过河流汇入大海的桥下。研究发现,铂(Pt)、钯(Pd)和铑(Rh)的高浓度与交通密度高的地区(贝波索)的水和土壤有关,这表明车辆也会向环境中排放重金属(铂族金属)。结果显示,这些金属在河岸、河床和水中的含量都有所升高。因此,这些金属有可能在这些区域的动植物体内积累。

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