Braescu Liliana
Department of Computer Science, Faculty of Mathematics and Computer Science, West University of Timisoara, Blv. V. Parvan 4, 300223 Timisoara, Romania.
J Colloid Interface Sci. 2008 Mar 1;319(1):309-15. doi: 10.1016/j.jcis.2007.11.016. Epub 2007 Dec 20.
Dewetted Bridgman is a crystal growth technique in which the crystal is detached from the crucible wall by a liquid free surface at the level of the solid-liquid interface, called liquid meniscus, which creates a gap between the crystal and the ampoule. Dewetting phenomenon was first obtained spontaneously in spatial experiments during the Bridgman solidification, and opened the possibility of reproducing experiments on the earth--obtained by applying a gas pressure difference Delta P=P cold-P hot between the cold and the hot sides of the sample. In order to understand the process which leads to a crystal with a constant radius on the ground, analytical and numerical studies of axisymmetric meniscus shapes are made and the dependence of the meniscus shape on the pressure difference is established. For this aim, starting from the Young-Laplace equation of a capillary surface in equilibrium in the presence of gas pressure, a mathematical model able to describe the meniscus surface z=z(r) and the angle theta=theta(r) between the tangent to the meniscus and the horizontal axis is presented. On the basis of this model, inequalities of the pressure intervals for which dewetting is feasible are established. Numerical results are performed for InSb crystals.
去湿布里奇曼法是一种晶体生长技术,在该技术中,晶体在固液界面处被一个称为液体弯月面的自由液体表面从坩埚壁上分离,这在晶体和安瓿之间形成了一个间隙。去湿现象最初是在布里奇曼凝固过程中的空间实验中自发获得的,并开启了在地球上重现实验的可能性——通过在样品的冷端和热端之间施加气压差ΔP = P冷 - P热来实现。为了理解在地面上获得具有恒定半径晶体的过程,对轴对称弯月面形状进行了分析和数值研究,并确定了弯月面形状对压力差的依赖性。为此,从存在气压时毛细管表面平衡的杨 - 拉普拉斯方程出发,提出了一个能够描述弯月面表面z = z(r)以及弯月面切线与水平轴之间夹角θ = θ(r)的数学模型。基于该模型,建立了去湿可行的压力区间不等式。对锑化铟晶体进行了数值计算。