Experimental vibrational spectra of gas-phase tantalum cluster cations.
作者信息
Gruene Philipp, Fielicke André, Meijer Gerard
机构信息
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany.
出版信息
J Chem Phys. 2007 Dec 21;127(23):234307. doi: 10.1063/1.2806177.
PMID:18154382
Abstract
We present gas-phase infrared spectra of tantalum cluster cations containing 6-20 atoms. Infrared multiple photon dissociation of their complexes with argon atoms is used to obtain vibrational spectra in the region between 90 and 305 cm(-1). Many spectra have features in common with the vibrational spectra of the lighter homologs, vanadium and niobium, pointing to a common cluster growth mechanism.
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