（三甲基硅基）三硅烷：作为一种基于自由基的还原剂被发现二十年后。
(Me3Si)3SiH: twenty years after its discovery as a radical-based reducing agent.
作者信息
Chatgilialoglu Chryssostomos
机构信息
ISOF, Consiglio Nazionale delle Ricerche, Via P. Gobetti 101, 40129 Bologna, Italy.
出版信息
Chemistry. 2008;14(8):2310-20. doi: 10.1002/chem.200701415.
PMID:18165952
Abstract
This Concept shows the flexibility and applicability of (Me3Si)3SiH in several synthetic transformations, such as radical reductions, consecutive radical reactions and hydrosilylation. The reactivity of (Me3Si)3SiH combines the multidisciplinary aspects of physical organic chemistry and organic synthesis, extending to polymers and materials science, as in the functionalization of flat silicon surfaces.
摘要
本概念展示了(Me3Si)3SiH在多种合成转化中的灵活性和适用性，例如自由基还原、连续自由基反应和硅氢化反应。(Me3Si)3SiH的反应性结合了物理有机化学和有机合成的多学科方面，并延伸到聚合物和材料科学领域，如在平面硅表面的功能化方面。
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