Brandon N P, Brett D J
Faculty of Engineering, Imperial College London, South Kensington campus, London SW7 2AZ, UK.
Philos Trans A Math Phys Eng Sci. 2006 Jan 15;364(1838):147-59. doi: 10.1098/rsta.2005.1684.
Porous materials play an important role in fuel cell engineering. For example, they are used to support delicate electrolyte membranes, where mechanical integrity and effective diffusivity to fuel gases is critical; they are used as gas diffusion layers, where electronic conductivity and permeability to both gas and water is critical; and they are used to construct fuel cell electrodes, where an optimum combination of ionic conductivity, electronic conductivity, porosity and catalyst distribution is critical. The paper will discuss these characteristics, and introduce the materials and processing methods used to engineer porous materials within two of the leading fuel cell variants, the solid oxide fuel cell and the polymer electrolyte membrane fuel cell.
多孔材料在燃料电池工程中发挥着重要作用。例如,它们被用于支撑脆弱的电解质膜,在这种情况下,机械完整性和对燃料气体的有效扩散率至关重要;它们被用作气体扩散层,在这种情况下,电子导电性以及对气体和水的渗透性至关重要;它们还被用于构建燃料电池电极,在这种情况下,离子导电性、电子导电性、孔隙率和催化剂分布的最佳组合至关重要。本文将讨论这些特性,并介绍用于在两种主要的燃料电池变体——固体氧化物燃料电池和聚合物电解质膜燃料电池中设计多孔材料的材料和加工方法。