二钌（II,III）双（四甲基-1,3-苯二丙酸酯）作为叔丁基过氧化氢氧化反应的新型催化剂。
Diruthenium(II,III) bis(tetramethyl-1,3-benzenedipropionate) as a novel catalyst for tert-butyl hydroperoxide oxygenation.
作者信息
Barker Julia E, Ren Tong
机构信息
Department of Chemistry, University of Miami, Coral Gables, Florida 33146, USA.
出版信息
Inorg Chem. 2008 Apr 7;47(7):2264-6. doi: 10.1021/ic800035w. Epub 2008 Mar 14.
The reaction of Ru2(OAc)4Cl with 2.2 equiv of H2esp (esp = alpha,alpha,alpha',alpha'-tetramethyl-1,3-benzenedipropionate) resulted in a new compound, Ru2(esp)2Cl (1), that is soluble in organic media. 1 is an active catalyst for the oxygenation of organic sulfides by tert-butyl hydroperoxide (TBHP) in both an acetonitrile solution or neat (solvent-free) conditions. Solvent-free reactions display the quantitative utility of TBHP and hence excellent chemical selectivity for sulfoxide formation.
Ru2(OAc)4Cl与2.2当量的H2esp（esp = α,α,α',α'-四甲基-1,3-苯二丙酸酯）反应生成了一种新化合物Ru2(esp)2Cl（1），它可溶于有机介质。1是一种活性催化剂，可在乙腈溶液或纯（无溶剂）条件下通过叔丁基过氧化氢（TBHP）将有机硫化物氧化。无溶剂反应显示出TBHP的定量效用，因此对亚砜形成具有出色的化学选择性。
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