An oxidative carbon-carbon bond formation system in cycloalkane-based thermomorphic multiphase solution.
作者信息
Kim Shokaku, Noda Satoko, Hayashi Kanako, Chiba Kazuhiro
机构信息
Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology, Tokyo, Japan.
出版信息
Org Lett. 2008 May 1;10(9):1827-9. doi: 10.1021/ol8004408. Epub 2008 Apr 1.
PMID:18376846
Abstract
A selective anodic oxidation system in which a carbocation intermediate is generated exclusively by use of a temperature-controlled multiphase solution to separate the different stages of the reaction from each other and from the products is described. The formation of a thermomorphic middle layer in an electrolytic solution composed of c-Hex and LPC/MeNO2 results in enhanced interaction between aliphatic alkenes and polar unstable cation.
摘要
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