Fu Chengyu, Liao Jinsheng, Luo Wenqin, Li Renfu, Chen Xueyuan
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Opt Lett. 2008 May 1;33(9):953-5. doi: 10.1364/ol.33.000953.
Er(3+)-ion-doped anatase TiO(2) nanocrystals were prepared by simple wet chemical synthesis. Very sharp and intense near-infrared luminescence at approximately 1.53 microm was observed that originated from the lattice site of Er(3+) ions incorporated in TiO(2) nanocrystals. Based on the high-resolution emission and excitation spectra at 10 K, an efficient energy transfer from the TiO(2) host to Er(3+) ions was verified. The luminescence decay for the I13/24-->I15/24 transition at 1.53 microm showed nonexponential characteristics, indicating a nonradiative relaxation to the defects in the nanocrystals, and the intrinsic lifetime of the I13/24 state was determined to be 1.56 ms.
通过简单的湿化学合成法制备了掺铒(Er(3+))的锐钛矿型二氧化钛(TiO₂)纳米晶体。观察到在约1.53微米处有非常尖锐且强烈的近红外发光,其源于掺入TiO₂纳米晶体中的Er(3+)离子的晶格位置。基于10 K下的高分辨率发射和激发光谱,证实了从TiO₂主体到Er(3+)离子的有效能量转移。1.53微米处I13/24-->I15/24跃迁的发光衰减呈现非指数特征,表明存在向纳米晶体中缺陷的无辐射弛豫,且I13/24态的固有寿命被确定为1.56毫秒。