在2、6、8位和4 - B取代位置上定制具有炔基官能团的硼二吡咯亚甲基染料的性质。

Tailoring the properties of boron-dipyrromethene dyes with acetylenic functions at the 2,6,8 and 4-B substitution positions.

作者信息

Bonardi Laure, Ulrich Gilles, Ziessel Raymond

机构信息

Laboratoire De Chimie Organique Et Spectroscopies Avancées, Centre National de la Recherche Scientifique, Université Louis Pasteur, Ecole de chimie, Polymères, Matériaux de Strasbourg, Strasbourg, France.

出版信息

Org Lett. 2008 Jun 5;10(11):2183-6. doi: 10.1021/ol800560b. Epub 2008 May 8.

DOI:10.1021/ol800560b

PMID:18461947

Abstract

Substitution of F-Bodipy with alkynylaryl residues at boron, at the pyrrolic core or at the meso position, provides unique tri-, tetra-, and pentasubstituted dyes. Substitution at the (pyrrolic) 2,6-positions provides substantial red shifts with quantum yields in the 40-90% range and excited-state lifetimes of 3-7 ns. ON/OFF fluorescence switching can be produced by protonation of dibutylamino subunits.

摘要

在硼原子、吡咯核心或中位用炔基芳基残基取代氟硼二吡咯，可得到独特的三取代、四取代和五取代染料。在（吡咯的）2,6-位进行取代会产生显著的红移，量子产率在40 - 90%范围内，激发态寿命为3 - 7纳秒。二丁基氨基亚基的质子化可实现荧光的开/关切换。