类聚轮烷金属有机框架中不寻常的平行和倾斜互锁模式。
Unusual parallel and inclined interlocking modes in polyrotaxane-like metal-organic frameworks.
作者信息
Yang Jin, Ma Jian-Fang, Batten Stuart R, Su Zhong-Min
机构信息
Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
出版信息
Chem Commun (Camb). 2008 May 21(19):2233-5. doi: 10.1039/b800199e. Epub 2008 Mar 10.
DOI:10.1039/b800199e
PMID:18463750
Abstract
We describe here two unusual polyrotaxane-like metal-organic frameworks of [Co2(1,3-bix)2(bpea)2] and [Cd4(1,4-bix)4(bpea)4] x 4H2O , where both species contain loops and rods that are interlaced in a highly rare "parallel" fashion in , but, uniquely, in an "inclined" fashion in .
摘要
我们在此描述了两种不同寻常的类聚轮烷金属有机框架，即[Co2(1,3 - bix)2(bpea)2]和[Cd4(1,4 - bix)4(bpea)4]·4H2O，其中这两种物质都含有环和棒，它们在[此处可能有遗漏信息]中以极罕见的“平行”方式交错排列，但独特的是，在[此处可能有遗漏信息]中以“倾斜”方式排列。
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