Kim Sung-Kyoung, Lee Haiwon
Department of Chemistry, Hanyang University, Seoul 133-791, Korea.
Ultramicroscopy. 2008 Sep;108(10):1005-8. doi: 10.1016/j.ultramic.2008.04.029. Epub 2008 May 8.
Thin films of chemically functionalized single-walled carbon nanotubes (SWNTs) were fabricated by using a direct current (dc) electrophoretic deposition method. SWNTs were shortened and then functionalized with acid chloride group to combine with the amine group-terminated gold substrate. Silica nanospheres with a diameter of about 190 nm were arrayed on gold substrate to pattern a thin SWNT film. Periodically patterned SWNT film was eventually produced and would be used in potential applications like electron emitters and large surface area electrodes.
采用直流电泳沉积法制备了化学功能化单壁碳纳米管(SWNTs)薄膜。将单壁碳纳米管缩短,然后用酰氯基团进行功能化处理,使其与胺基端接的金基底相结合。将直径约为190 nm的二氧化硅纳米球排列在金基底上,以形成单壁碳纳米管薄膜的图案。最终制备出周期性图案化的单壁碳纳米管薄膜,该薄膜将用于电子发射器和大表面积电极等潜在应用中。