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氧化蜡作为线性低密度聚乙烯-粘土纳米复合材料的增容剂:X射线衍射和动态力学分析

Oxidized wax as compatibilizer in linear low-density polyethylene-clay nanocomposites: x-ray diffraction and dynamic mechanical analysis.

作者信息

Geethamma V G, Luyt Adriaan S

机构信息

Department of Chemistry, University of the Free State (Qwaqwa Campus), Private Bag X13, Phutthaditjhaba 9866, South Africa.

出版信息

J Nanosci Nanotechnol. 2008 Apr;8(4):1886-94.

Abstract

Oxidized paraffin wax was used as a compatibilizer in composites of linear low-density polyethylene and layered nano silicate clays. X-ray diffraction analyses were carried out to investigate the crystalline morphology of five types of clays, oxidized wax, and their composites with LLDPE. The composites exhibited different X-ray diffraction and dynamic mechanical behaviour in the presence of different clays. Generally, the composites retained the partially crystalline behaviour of LLDPE, and no exfoliation was observed. Increased amount of wax did not change the morphology in most cases. The incorporation of clay resulted in an observable increase in the storage modulus of LLDPE. These values also increased with the addition of oxidized wax for most of the composites. The loss modulus increased with the amount of clay, irrespective of its nature. In most cases these values also increased with the incorporation of wax. The composites with 10% clay and 10% oxidized wax showed the highest storage and loss moduli, irrespective of the nature of the clay. The tan delta values did not change considerably with the addition of clay or wax.

摘要

氧化石蜡被用作线性低密度聚乙烯与层状纳米硅酸盐黏土复合材料的增容剂。进行了X射线衍射分析,以研究五种黏土、氧化蜡及其与线性低密度聚乙烯复合材料的结晶形态。在不同黏土存在的情况下,复合材料表现出不同的X射线衍射和动态力学行为。一般来说,复合材料保留了线性低密度聚乙烯的部分结晶行为,且未观察到剥离现象。在大多数情况下,蜡用量的增加并未改变形态。黏土的加入导致线性低密度聚乙烯的储能模量有明显增加。对于大多数复合材料而言,这些值也随着氧化蜡的添加而增加。损耗模量随黏土用量增加而增加,与黏土的性质无关。在大多数情况下,这些值也随着蜡的加入而增加。含10%黏土和10%氧化蜡的复合材料显示出最高的储能模量和损耗模量,与黏土的性质无关。损耗角正切值并未因黏土或蜡的添加而发生显著变化。

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