Washburn K E, Eccles C D, Callaghan P T
School of Chemical and Physical Sciences, Victoria University of Wellington, P.O. Box 600, Wellington 6001, New Zealand.
J Magn Reson. 2008 Sep;194(1):33-40. doi: 10.1016/j.jmr.2008.05.025. Epub 2008 Jun 4.
Magnetic susceptibility differences in porous media produce local gradients within the pore space. At high magnetic fields, these inhomogeneities have the potential to greatly affect nuclear magnetic resonance measurements. We undertake a study using a new NMR technique to measure the internal gradients present in highly heterogeneous samples over a wide range of magnetic field strengths. Our results show that even at ultra-high fields there can exist signal at internal gradient strengths sufficiently small that techniques for suppressing unwanted side effects have the possibility to be used. Our findings encourage the use of these high and ultra-high field strengths for a broader range of samples. Our results also give experimental evidence to support the theory of internal gradient scaling as a function of field strength within pores.
多孔介质中的磁化率差异会在孔隙空间内产生局部梯度。在高磁场下,这些不均匀性有可能极大地影响核磁共振测量。我们采用一种新的核磁共振技术进行研究,以测量在广泛磁场强度范围内高度非均质样品中存在的内部梯度。我们的结果表明,即使在超高场下,内部梯度强度足够小的情况下仍可能存在信号,这使得抑制不需要的副作用的技术有可能被使用。我们的发现鼓励在更广泛的样品中使用这些高场和超高场强度。我们的结果还提供了实验证据,以支持内部梯度随孔隙内场强变化的标度理论。