Merkin J H
Department of Applied Mathematics, University of Leeds, Leeds, LS2 9JT, United Kingdom.
J Chem Phys. 2008 Jul 21;129(3):034507. doi: 10.1063/1.2953313.
A linear stability analysis of planar reaction fronts to transverse perturbations is considered for a system based on an autocatalytic reaction of general order p. Dispersion curves, plots of the growth rate sigma against a transverse wavenumber k, are obtained for a range of values of p and D, where D is the ratio of the diffusion coefficients of autocatalyst and substrate. A value D(0) of D, dependent on p, is found at which sigma(max), the maximum value of sigma in the unstable regime, is largest, with D(0) increasing as p is increased. An asymptotic analysis for small wavenumbers is derived, which enables the region in the (p, D) parameter space for instability to be determined. An analysis for D small is undertaken, which leads to upper bounds on the wavenumber for a possible instability.
针对基于一般阶数为p的自催化反应的系统,考虑平面反应前沿对横向扰动的线性稳定性分析。对于一系列p和D的值(其中D是自催化剂与底物扩散系数之比),得到了色散曲线,即增长率σ相对于横向波数k的曲线图。发现了一个依赖于p的D值D(0),在该值处,不稳定区域中σ的最大值σ(max)最大,且D(0)随p的增加而增大。推导了小波数的渐近分析,这使得能够确定(p, D)参数空间中不稳定的区域。对小D值进行了分析,这给出了可能不稳定的波数的上限。