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在DNA支架上微波合成导电金纳米线。

Microwave synthesis of electrically conductive gold nanowires on DNA scaffolds.

作者信息

Kundu Subrata, Liang Hong

机构信息

Materials Science and Mechanical Engineering, Texas A&M University, College Station, Texas 77843-3123, USA.

出版信息

Langmuir. 2008 Sep 2;24(17):9668-74. doi: 10.1021/la801633r. Epub 2008 Aug 1.

Abstract

Biological molecules, in particular DNA, have shown great potential to be used as interconnects of nanodevices and computational elements. In this research, we synthesized electrically conductive gold nanowires for the first time exploiting an electroless and microwave heating method for 120-180 s. Our results indicate that DNA serves as a reducing and nonspecific capping agent for the growth of nanowires. The current voltage ( I- V) characteristics of the Au nanowires are continuous, exhibiting Ohmic behavior having low contact resistance with the gold electrodes. The nanowires have a diameter of 10-15 nm in solution and of 20-30 nm in immobilized DNA with resistivity comparable to pure metals. The method is highly selective with deposition confined to the DNA itself. The nanowires we fabricated can be used as building blocks for functional nanodevices, sensors, and optoelectronics.

摘要

生物分子,尤其是DNA,已显示出作为纳米器件和计算元件互连的巨大潜力。在本研究中,我们首次利用无电镀和微波加热方法120 - 180秒合成了导电金纳米线。我们的结果表明,DNA作为纳米线生长的还原剂和非特异性封端剂。金纳米线的电流 - 电压(I - V)特性是连续的,呈现出与金电极具有低接触电阻的欧姆行为。纳米线在溶液中的直径为10 - 15纳米,在固定化DNA中的直径为20 - 30纳米,其电阻率与纯金属相当。该方法具有高度选择性,沉积仅限于DNA本身。我们制造的纳米线可用作功能性纳米器件、传感器和光电子学的构建块。

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