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中国北京沙尘暴沉积物中的多氯联苯残留

Polychlorinated biphenyl residues in sandstorm depositions in Beijing, China.

作者信息

Fu Shan, Yang Zhong-Zhi, Li Ke, Xu Xiao-Bai

机构信息

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Post Office Box 2871, Beijing 100085, People's Republic of China.

出版信息

Chemosphere. 2008 Oct;73(6):962-6. doi: 10.1016/j.chemosphere.2008.06.049. Epub 2008 Jul 31.

Abstract

Sandstorms, which distribute many particles, are a special atmospheric occurrence and are frequent in northern China. We conducted this study to determine, for the first time, the concentration of polychlorinated biphenyls (PCBs) in sandstorm depositions. We collected 13 samples from urban areas of Beijing, and we measured a total of 144 PCB congeners. Thirteen samples all contained PCB residues. The total PCB concentration ranged from 1.6 to 15.6ngg(-1) (median, 4.8ngg(-1), dry weight), with trichlorinated biphenyls as the predominant homologue (>50.4%). Furthermore, we observed increasing PCB contamination from northwest to east Beijing. We later explored possible factors affecting contamination of the sandstorm depositions, which revealed a significant correlation between SigmaPCBs and the minimum particle size of the sandstorm deposition samples. Principal-component analysis revealed that the major source of PCBs in Beijing may be potentially associated with the number-one commercial PCB through the long-range transmission. In previous results, PCBs were not a severe component of contamination in sandstorm depositions of Beijing. However, this study suggested that sandstorm deposition may be a potential source of exposure to PCBs for the residents of Beijing, China.

摘要

沙尘暴会散布许多颗粒物,是一种特殊的大气现象,在中国北方频繁发生。我们开展这项研究,首次测定沙尘暴沉积物中多氯联苯(PCBs)的浓度。我们从北京城区采集了13个样本,共检测了144种多氯联苯同系物。13个样本均含有多氯联苯残留。多氯联苯总浓度范围为1.6至15.6纳克/克(中位数为4.8纳克/克,干重),其中三氯联苯为主要同系物(>50.4%)。此外,我们观察到北京从西北到东部多氯联苯污染呈上升趋势。我们随后探究了影响沙尘暴沉积物污染的可能因素,结果显示多氯联苯总量与沙尘暴沉积物样本的最小粒径之间存在显著相关性。主成分分析表明,北京多氯联苯的主要来源可能与头号商用多氯联苯通过长距离传输存在潜在关联。在之前的研究结果中,多氯联苯并非北京沙尘暴沉积物中严重的污染成分。然而,本研究表明,沙尘暴沉积物可能是中国北京居民接触多氯联苯的一个潜在来源。

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