Sibly T F, Unsworth A
Centre for Biomedical Engineering, School of Engineering and Applied Science, University of Durham, UK.
J Biomed Eng. 1991 May;13(3):217-20. doi: 10.1016/0141-5425(91)90130-y.
Cross-linking of polyethylene (XLPE) has dramatically improved its properties in industrial applications, and it may also have some application in the field of human joint replacement. Additionally it has the advantage of permitting a lower molecular weight base material to be used, so that components may be injection moulded rather than machined. This study therefore investigates the wear resistance of medical grade cross-linked polyethylene (XLPE), cross-linked by a silane-grafting process, with a molecular weight between cross links of 5430 g mol(-1). This first report investigates the wear resistance of XLPE against itself, because for certain joints, such as the metacarpo-phalangeal joint, the material may have a high enough wear resistance to allow both bearing surfaces to be made from it. Tests were carried out both on a reciprocating pin and plate machine with pins loaded at 10 and 40 N and also on a new finger joint simulator, which simulates the loads applied to and the movements of, the metacarpo-phalangeal joint. An average wear rate of 1.8 x 10(-6) mm3 N-1 m-1 was found (range 0.9-2.75 x 10(-6) mm3 N-1 m-1). This is about six times greater than the wear rate of non-cross-linked ultra high molecular weight polyethylene (UHMWPE) against stainless steel, but for applications with low loading, such as the metacarpo-phalangeal joint, this material is shown to have adequate wear resistance. The coefficient of friction was 0.1, which is similar to that of UHMWPE on stainless steel.
聚乙烯交联(XLPE)显著改善了其在工业应用中的性能,并且在人类关节置换领域可能也有一些应用。此外,它具有允许使用较低分子量基础材料的优点,这样部件可以通过注塑成型而非机械加工。因此,本研究调查了通过硅烷接枝工艺交联的医用级交联聚乙烯(XLPE)的耐磨性,其交联点间分子量为5430 g mol(-1)。这第一篇报告研究了XLPE自身的耐磨性,因为对于某些关节,如掌指关节,该材料可能具有足够高的耐磨性,使得两个承载表面都可以由其制成。测试在往复销盘机上进行,销上加载10 N和40 N的力,同时也在一种新型手指关节模拟器上进行,该模拟器模拟施加到掌指关节的载荷和运动。发现平均磨损率为1.8×10(-6) mm3 N-1 m-1(范围为0.9 - 2.75×10(-6) mm3 N-1 m-1)。这大约是非交联超高分子量聚乙烯(UHMWPE)对不锈钢磨损率的六倍,但对于低载荷应用,如掌指关节,该材料显示出足够的耐磨性。摩擦系数为0.1,这与UHMWPE在不锈钢上的摩擦系数相似。