Chen Yu-Cheng, Tsai Perng-Jy, Mou Jin-Luh
Department of Environmental and Occupational Health, Medical College, National Cheng Kung University, 138, Sheng-Li Road, Tainan 70428, Taiwan.
Environ Sci Technol. 2008 Jul 15;42(14):5298-303. doi: 10.1021/es703245d.
This study is the first one using the Taguchi experimental design to identify the optimal operating condition for reducing polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/ Fs) formations during the iron ore sintering process. Four operating parameters, including the water content (Wc; range = 6.0-7.0 wt %), suction pressure (Ps; range = 1000-1400 mmH2O), bed height (Hb; range = 500-600 mm), and type of hearth layer (including sinter, hematite, and limonite), were selected for conducting experiments in a pilot scale sinter pot to simulate various sintering operating conditions of a real-scale sinter plant We found that the resultant optimal combination (Wc = 6.5 wt%, Hb = 500 mm, Ps = 1000 mmH2O, and hearth layer = hematite) could decrease the emission factor of total PCDD/Fs (total EF(PCDD/Fs)) up to 62.8% by reference to the current operating condition of the real-scale sinter plant (Wc = 6.5 wt %, Hb = 550 mm, Ps = 1200 mmH2O, and hearth layer = sinter). Through the ANOVA analysis, we found that Wc was the most significant parameter in determining total EF(PCDD/Fs (accounting for 74.7% of the total contribution of the four selected parameters). The resultant optimal combination could also enhance slightly in both sinter productivity and sinter strength (30.3 t/m2/day and 72.4%, respectively) by reference to those obtained from the reference operating condition (29.9 t/m (2)/day and 72.2%, respectively). The above results further ensure the applicability of the obtained optimal combination for the real-scale sinter production without interfering its sinter productivity and sinter strength.
本研究首次采用田口实验设计来确定在铁矿石烧结过程中减少多氯代二苯并 - 对 - 二噁英和二苯并呋喃(PCDD/Fs)生成的最佳操作条件。选择了四个操作参数进行中试规模烧结锅实验,以模拟实际规模烧结厂的各种烧结操作条件,这四个参数包括含水量(Wc;范围 = 6.0 - 7.0 wt%)、抽吸压力(Ps;范围 = 1000 - 1400 mmHg₂O)、料层高度(Hb;范围 = 500 - 600 mm)以及炉床层类型(包括烧结矿、赤铁矿和褐铁矿)。我们发现,与实际规模烧结厂的当前操作条件(Wc = 6.5 wt%,Hb = 550 mm,Ps = 1200 mmHg₂O,炉床层 = 烧结矿)相比,所得的最佳组合(Wc = 6.5 wt%,Hb = 500 mm,Ps = 1000 mmHg₂O,炉床层 = 赤铁矿)可使总PCDD/Fs排放因子(总EF(PCDD/Fs))降低高达62.8%。通过方差分析,我们发现Wc是决定总EF(PCDD/Fs)的最显著参数(占所选四个参数总贡献的74.7%)。与参考操作条件下获得的结果(分别为29.9 t/m²/天和72.2%)相比,所得的最佳组合还可使烧结生产率和烧结强度略有提高(分别为30.3 t/m²/天和72.4%)。上述结果进一步确保了所得最佳组合在不影响实际规模烧结生产的烧结生产率和烧结强度的情况下适用于实际烧结生产。