两种具有新型七核金属羧酸盐簇的高度连接的手性多孔配位聚合物。
Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters.
作者信息
Hou Lei, Zhang Jie-Peng, Chen Xiao-Ming, Ng Seik Weng
机构信息
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China.
出版信息
Chem Commun (Camb). 2008 Sep 14(34):4019-21. doi: 10.1039/b809069f. Epub 2008 Aug 4.
DOI:10.1039/b809069f
PMID:18758612
Abstract
Two novel (3,12)-connected, chiral porous coordination polymers featuring 3D intersecting pore structures, selective sorption and solvothermal resistance properties are constructed by linking 3-connected benzene-1,3,5-tribenzoic acid with two types of 12-connected heptanuclear metal carboxylate clusters.
摘要
通过将三连接的苯-1,3,5-三苯甲酸与两种十二连接的七核金属羧酸盐簇相连，构建了两种具有三维交叉孔结构、选择性吸附和溶剂热稳定性的新型（3,12）连接的手性多孔配位聚合物。
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