α-取代的反式α,β-二氨基膦酸衍生物的非对映和对映选择性合成。
A diastereo- and enantioselective synthesis of alpha-substituted anti-alpha,beta-diaminophosphonic acid derivatives.
作者信息
Wilt Jeremy C, Pink Maren, Johnston Jeffrey N
机构信息
Department of Chemistry and Vanderbilt Institute of Chemical Biology, Vanderbilt University, Nashville, TN 37235-1822, USA.
出版信息
Chem Commun (Camb). 2008 Sep 21(35):4177-9. doi: 10.1039/b808393b. Epub 2008 Aug 6.
DOI:10.1039/b808393b
PMID:18802521
Abstract
Highly diastereo- and enantioselective additions of alpha-nitrophosphonates to imines catalyzed by a chiral Brønsted acid are described.
摘要
描述了在手性布朗斯特酸催化下，α-硝基膦酸酯对亚胺的高度非对映和对映选择性加成反应。
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