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在悬浮生长生物反应器中对皮革工业污染废气进行生物处理。

Biological treatment of a contaminated gaseous emission from a leather industry in a suspended-growth bioreactor.

作者信息

Carvalho M F, Duque A F, Moura S C, Amorim C L, Ferreira Jorge R M, Castro P M L

机构信息

Escola Superior de Biotecnologia, Universidade Católica Portuguesa, Rua Dr. António Bernardino de Almeida, 4200-072 Porto, Portugal.

出版信息

Chemosphere. 2009 Jan;74(2):232-8. doi: 10.1016/j.chemosphere.2008.09.047. Epub 2008 Nov 5.

Abstract

A suspended-growth bioreactor (SGB) was operated for the treatment of a gaseous stream mimicking emissions generated at a leather industrial company. The main volatile organic compounds (VOCs) present in the gaseous stream consisted of 1-methoxy-2-propanol, 2,6-dimethyl-4-heptanone, 2-butoxyethanol, toluene and butylacetate. A microbial consortium able to degrade these VOCs was successfully enriched. A laboratory-scale SGB was established and operated for 210-d with an 8h cycle period and with shutdowns at weekends. Along this period, the SGB was exposed to organic loads (OL) between 6.5 and 2.3 x 10(2) g h(-1) m(-3). Most of the compounds were not detected at the outlet of the SGB. The highest total VOC removal efficiency (RE) (ca 99%) was observed when an OL of 1.6 x 10(2) g h(-1) m(-3) was fed to the SGB. The maximum total VOC elimination capacity (1.8 x 10(2) g h(-1) m(-3)) was achieved when the OL applied to the SGB was 2.3 x 10(2) g h(-1) m(-3). For all the operating conditions, the SGB showed high levels of degradation of toluene and butylacetate (RE approximately equal to 100%). This study also revealed that recirculation of the gaseous effluent improved the performance of the SGB. Overall, the SGB was shown to be robust, showing high performance after night and weekend shutdown periods.

摘要

运行了一个悬浮生长生物反应器(SGB),用于处理模拟皮革工业公司产生的排放气流。气流中存在的主要挥发性有机化合物(VOCs)包括1-甲氧基-2-丙醇、2,6-二甲基-4-庚酮、2-丁氧基乙醇、甲苯和乙酸丁酯。成功富集了一个能够降解这些VOCs的微生物群落。建立了一个实验室规模的SGB,并以8小时的周期运行210天,周末停机。在此期间,SGB暴露于6.5至2.3×10² g h⁻¹ m⁻³之间的有机负荷(OL)。在SGB的出口未检测到大多数化合物。当向SGB进料1.6×10² g h⁻¹ m⁻³的OL时,观察到最高的总VOC去除效率(RE)(约99%)。当应用于SGB的OL为2.3×10² g h⁻¹ m⁻³时,实现了最大的总VOC消除能力(1.8×10² g h⁻¹ m⁻³)。对于所有运行条件,SGB对甲苯和乙酸丁酯均表现出高水平的降解(RE约等于100%)。该研究还表明,气态流出物的再循环提高了SGB的性能。总体而言,SGB表现出很强的稳定性,在夜间和周末停机后仍具有高性能。

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