三维镧系金属有机框架：结构、光致发光和磁性。
3-D lanthanide metal-organic frameworks: structure, photoluminescence, and magnetism.
作者信息
Black Cory A, Costa José Sánchez, Fu Wen Tian, Massera Chiara, Roubeau Olivier, Teat Simon J, Aromí Guillem, Gamez Patrick, Reedijk Jan
机构信息
Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.
出版信息
Inorg Chem. 2009 Feb 2;48(3):1062-8. doi: 10.1021/ic8017826.
A series of isostructural three-dimensional metal-organic frameworks Pr(2)(N-BDC)(3)(dmf)(4) (1), {[Eu(2)(N-BDC)(3)(dmf)(4)] x 2DMF}(infinity) (2 x 2DMF), Gd(2)(N-BDC)(3)(dmf)(4) (3), {[Tb(2)(N-BDC)(3)(dmf)(4)] x 2DMF}(infinity) (4 x 2DMF), {[Dy(2)(N-BDC)(3)(dmf)(4)] x 2DMF}(infinity) (5 x 2DMF) (N-H(2)BDC = 2-amino-1,4-benzenedicarboxylic acid; DMF = N,N'-dimethylformamide) with cubic 4(12) x 6(3) topology have been synthesized using solvothermal conditions. The networks were generated via formation of a dinuclear Ln(2) secondary building block, involving the dicarboxylate ligand as a bridge. The luminescent properties of the Tb(III) and Eu(III) complexes were studied and showed characteristic emissions at room temperature. Antiferromagnetic interactions between Ln(III) ions were observed from magnetic susceptibility data.
通过溶剂热条件合成了一系列具有立方4(12)×6(3)拓扑结构的同构三维金属有机骨架Pr(2)(N-BDC)(3)(dmf)(4) (1)、{[Eu(2)(N-BDC)(3)(dmf)(4)]×2DMF}(无穷大) (2×2DMF)、Gd(2)(N-BDC)(3)(dmf)(4) (3)、{[Tb(2)(N-BDC)(3)(dmf)(4)]×2DMF}(无穷大) (4×2DMF)、{[Dy(2)(N-BDC)(3)(dmf)(4)]×2DMF}(无穷大) (5×2DMF)（N-H(2)BDC = 2-氨基-1,4-苯二甲酸；DMF = N,N'-二甲基甲酰胺）。这些网络是通过形成双核Ln(2)二级结构单元生成的，其中二羧酸配体作为桥连。研究了Tb(III)和Eu(III)配合物的发光性质，结果表明它们在室温下有特征发射。从磁化率数据观察到Ln(III)离子之间的反铁磁相互作用。
Zotero 插件