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通过声吸附法可从二元水溶液中同时去除镉离子和铅离子。

Cadmium and lead ions can be removed simultaneously from a binary aqueous solution by the sono-sorption method.

作者信息

Entezari M H, Soltani T

机构信息

Department of Chemistry, Ferdowsi University of Mashhad, 91775 Mashhad, Iran.

出版信息

Ultrason Sonochem. 2009 Apr;16(4):495-501. doi: 10.1016/j.ultsonch.2008.12.001. Epub 2008 Dec 11.

Abstract

This paper presents the effect of ultrasound on the simultaneous removal of Cd(2+) and Pb(2+) ions from a binary aqueous solution in the presence of natural sorbent (sono-sorption method). The obtained results compare with the results of control method which was achieved in the absence of ultrasound. The experiments under sonication were carried out by 20 kHz apparatus. The effect of different parameters such as the amount of sorbent, contact time, temperature, and specially the competitive sorption of ions were considered for both methods. It is found that the sorption efficiency of Cd(2+) was decreased in the presence of Pb(2+). But, the presence of Cd(2+) had a negligible effect on the removal of Pb(2+). The results show that in the binary solution, the removal efficiency was higher in the presence of ultrasound than the control method. Both ions in binary solution can be removed to near completion with ultrasound. Two different multi-component isotherm equations based on the Langmuir isotherm were applied on the studied system to predict the sorption behavior of the components.

摘要

本文介绍了在天然吸附剂存在下,超声对从二元水溶液中同时去除Cd(2+)和Pb(2+)离子的影响(超声吸附法)。将所得结果与在无超声条件下实现的对照方法的结果进行比较。超声处理下的实验通过20 kHz仪器进行。两种方法都考虑了不同参数的影响,如吸附剂用量、接触时间、温度,特别是离子的竞争吸附。研究发现,在Pb(2+)存在下,Cd(2+)的吸附效率降低。但是,Cd(2+)的存在对Pb(2+)的去除影响可忽略不计。结果表明,在二元溶液中,超声存在下的去除效率高于对照方法。二元溶液中的两种离子在超声作用下均可接近完全去除。基于朗缪尔等温线的两种不同的多组分等温方程应用于所研究的体系,以预测各组分的吸附行为。

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