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一种用于环境清理的有吸引力的农业工业副产品:未处理橄榄果渣的染料生物吸附潜力。

An attractive agro-industrial by-product in environmental cleanup: dye biosorption potential of untreated olive pomace.

作者信息

Akar Tamer, Tosun Ilknur, Kaynak Zerrin, Ozkara Esra, Yeni Onur, Sahin Esin N, Akar Sibel Tunali

机构信息

Department of Chemistry, Faculty of Arts and Science, Eskişehir Osmangazi University, Campus of Meselik, 26480 Eskişehir, Turkey.

出版信息

J Hazard Mater. 2009 Jul 30;166(2-3):1217-25. doi: 10.1016/j.jhazmat.2008.12.029. Epub 2008 Dec 9.

Abstract

This research deals with the evaluation of highly available and cost effective waste biomass of olive pomace for the removal of reactive textile dye, RR198 from aqueous medium and a real effluent. The experiments were conducted to assess the effects of process variables such as initial pH, biosorbent dosage, contact time, temperature and ionic strength. The results showed that the highest dye biosorption capacity was found at pH 2 and the needed time to reach the biosorption equilibrium was 40 min with a biosorbent concentration of 3.0 g L(-1). The sorption kinetics of dye was best described by the pseudo-second-order kinetic model. The equilibrium biosorption data were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich isotherm models and the results from the isotherm studies showed that the RR198 biosorption process occurred on a homogenous surface of the biosorbent. The waste biomass of olive oil industry displayed biosorption capacities ranging from 6.05 x 10(-5) to 1.08 x 10(-4)mol g(-1) at different temperatures. The negative values of Delta G degrees and the positive value of Delta H degrees suggest that the biosorption process for RR198 was spontaneous and endothermic. Dye-biosorbent interactions were examined by FTIR and SEM analysis. Finally, high biosorption yield of olive waste for the removal of RR198 dye from real wastewater makes it possible that the olive pomace could be applied widely in wastewater treatment as biosorbent taking into account that no pretreatment on the solid residue is carried out.

摘要

本研究旨在评估高可用性且经济高效的橄榄果渣废弃生物质对活性纺织染料RR198从水介质及实际废水中的去除效果。进行了一系列实验以评估诸如初始pH值、生物吸附剂用量、接触时间、温度和离子强度等工艺变量的影响。结果表明,在pH值为2时染料生物吸附容量最高,在生物吸附剂浓度为3.0 g L(-1)的情况下,达到生物吸附平衡所需时间为40分钟。染料的吸附动力学最好用准二级动力学模型来描述。通过朗缪尔、弗伦德利希和杜宾宁-拉杜舍维奇等温线模型对平衡生物吸附数据进行了分析,等温线研究结果表明RR198生物吸附过程发生在生物吸附剂的均匀表面上。橄榄油工业的废弃生物质在不同温度下的生物吸附容量范围为6.05×10(-5)至1.08×10(-4)mol g(-1)。ΔG°的负值和ΔH°的正值表明RR198的生物吸附过程是自发的且为吸热过程。通过傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)分析研究了染料与生物吸附剂之间的相互作用。最后,考虑到对固体残渣未进行预处理,橄榄果渣对实际废水中RR198染料具有高生物吸附产率,这使得橄榄果渣作为生物吸附剂有可能广泛应用于废水处理。

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