带有β-酮亚胺基和β-二酮亚胺基配体的半三明治型铬（III）配合物作为乙烯聚合催化剂。
Half-sandwich chromium(III) complexes bearing beta-ketoiminato and beta-diketiminate ligands as catalysts for ethylene polymerization.
作者信息
Huang Yuan-Biao, Jin Guo-Xin
机构信息
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Advanced Materials Laboratory, Fudan University, Shanghai, 200 433, China.
出版信息
Dalton Trans. 2009 Feb 7(5):767-9. doi: 10.1039/b820798b. Epub 2008 Dec 12.
DOI:10.1039/b820798b
PMID:19156267
Abstract
Half-sandwich chromium(iii) complexes bearing beta-ketoiminato and beta-diketiminate ligands were synthesized and employed as catalysts for ethylene polymerization in the presence of triethylaluminium.
摘要
合成了带有β-酮亚胺基和β-二酮亚胺基配体的半三明治型铬（III）配合物，并将其用作在三乙基铝存在下乙烯聚合的催化剂。
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