通过普林斯-傅克反应立体选择性一锅法合成4-芳基四氢吡喃的三组分反应
Stereoselective one-pot, three-component synthesis of 4-aryltetrahydropyran via Prins-Friedel-Crafts reaction.
作者信息
Reddy U C, Bondalapati S, Saikia Anil K
机构信息
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India.
出版信息
J Org Chem. 2009 Mar 20;74(6):2605-8. doi: 10.1021/jo802531h.
PMID:19216514
Abstract
A diastereoselective one-pot, three-component Prins-Friedel-Crafts reaction was developed for the synthesis of 4-aryltetrahydropyran derivatives from the reaction of carbonyl compounds with homoallylic alcohol in the presence of arene promoted by boron trifluoride etherate.
摘要
开发了一种非对映选择性的一锅三组分普林斯-傅克反应，用于在三氟化硼乙醚促进的芳烃存在下，由羰基化合物与高烯丙醇反应合成4-芳基四氢吡喃衍生物。
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