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基于类水滑石化合物的新型混合氧化物催化剂上的氮氧化物分解、储存及还原

NO(x) decomposition, storage and reduction over novel mixed oxide catalysts derived from hydrotalcite-like compounds.

作者信息

Yu Jun Jie, Cheng Jie, Ma Chun Yan, Wang Hai Lin, Li Lan Dong, Hao Zheng Ping, Xu Zhi Ping

机构信息

Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, PR China.

出版信息

J Colloid Interface Sci. 2009 May 15;333(2):423-30. doi: 10.1016/j.jcis.2009.02.022. Epub 2009 Feb 12.

Abstract

Effective control and removal of nitrogen oxides (NO(x)) emission from vehicles exhausts under lean-burn condition is one of the most important targets in scientific research of environmental protection. A comprehensive introduction of NO(x) storage and reduction (NSR), the most promising lean-NO(x) control technology, is given including the sum-up of NSR materials, catalytic activity and related reaction mechanisms. Emphasis is put on the novel multifunctional NSR catalysts, derived from hydrotalcite-like compounds, with characteristic of simultaneous NO(x) strorage-decomposition-reduction. Finally, future research directions in the area of lean-NO(x) control based on mixed oxide catalysts derived from hydrotalcite-like materials is also proposed.

摘要

在贫燃条件下有效控制和去除车辆尾气中的氮氧化物(NO(x))排放是环境保护科学研究的最重要目标之一。本文全面介绍了最具前景的贫燃氮氧化物控制技术——氮氧化物储存与还原(NSR),包括NSR材料、催化活性及相关反应机理的总结。重点介绍了源自类水滑石化合物的新型多功能NSR催化剂,其具有同时进行NO(x)储存-分解-还原的特性。最后,还提出了基于类水滑石材料衍生的混合氧化物催化剂的贫燃氮氧化物控制领域的未来研究方向。

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