Bodega P S, Alonso S, Rotermund H H
Fritz-Haber Institute of the Max Planck Society, Faradayweg 4-6, 14195 Berlin, Germany.
J Chem Phys. 2009 Feb 28;130(8):084704. doi: 10.1063/1.3078037.
Oxidation reaction of CO on a single platinum crystal is a reaction-diffusion system that may exhibit bistable, excitable, and oscillatory behavior. We studied the effect of a stochastic signal artificially introduced into the system through the partial pressure of CO. First, the external signal is employed as a turbulence suppression tool, and second, it modifies the boundaries in the bistable transition between the CO and oxygen covered phases. Experiments using photoemission electron microscopy together with numerical simulations performed with the Krischer-Eiswirth-Ertl model are presented.
一氧化碳在单个铂晶体上的氧化反应是一个反应扩散系统,可能表现出双稳态、可激发和振荡行为。我们研究了通过一氧化碳分压人为引入系统的随机信号的影响。首先,将外部信号用作湍流抑制工具,其次,它改变了一氧化碳覆盖相和氧气覆盖相之间双稳态转变的边界。本文展示了使用光发射电子显微镜进行的实验以及用Krischer-Eiswirth-Ertl模型进行的数值模拟。