构建螺缩酮的杂环狄尔斯-阿尔德方法。
The hetero-Diels-Alder approach to spiroketals.
作者信息
Rizzacasa Mark A, Pollex Annett
机构信息
School of Chemistry, Bio21 Institute, 30 Flemington Rd, The University of Melbourne, 3010 Victoria, Australia.
出版信息
Org Biomol Chem. 2009 Mar 21;7(6):1053-9. doi: 10.1039/b819966n. Epub 2009 Feb 17.
DOI:10.1039/b819966n
PMID:19262920
Abstract
The hetero-Diels-Alder reaction can provide spiroketal systems with excellent stereoselectivity. This perspective article will briefly outline the scope and limitations of this approach for the production of naturally occurring spiroketals and derivatives.
摘要
杂环狄尔斯-阿尔德反应能够以优异的立体选择性构建螺缩酮体系。这篇综述文章将简要概述该方法在天然螺缩酮及其衍生物合成中的适用范围和局限性。
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