Sore Hannah F, Boehner Christine M, MacDonald Simon J F, Norton David, Fox David J, Spring David R
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.
Org Biomol Chem. 2009 Mar 21;7(6):1068-72. doi: 10.1039/b900852g. Epub 2009 Jan 23.
Vinyldisiloxanes equilibrate with the corresponding silanolates under basic conditions and subsequently undergo palladium catalysed cross coupling with aryl/heteroaryl iodides and bromides.
乙烯基二硅氧烷在碱性条件下与相应的硅醇盐达到平衡,随后在钯催化下与芳基/杂芳基碘化物和溴化物发生交叉偶联反应。