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[利用可调谐二极管激光吸收光谱法监测燃烧过程中一氧化碳浓度的变化]

[Monitoring the change in CO concentration in combustion with tunable diode laser absorption spectroscopy].

作者信息

Xia Hui, Liu Wen-Qing, Zhang Yu-Jun, Kan Rui-Feng, Chen Dong, Cui Yi-Ben, He Ying, Chen Jiu-Ying, Wang Min, Wang Tie-Dong

机构信息

Key Lab of Environmental Optics & Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Nov;28(11):2478-81.

Abstract

In the present paper, the technology of tunable diode laser absorption spectroscopy (TDLAS) in conjunction with the open path multi-pass Herriot cell and the new-style detection method of auto-balanced detection combined with wavelength modulation technology were used, and the concentration of CO produced in combustion of alcohol blowtorch was measured. It was found in the measured result that the change in CO concentration in the flame of alcohol blowtorch presented a stated periodicity in the process of combustion and the average concentration of CO was calculated to be 49.4 (10(-6) ratio by volume). The experiment is showed that with the conjunction of auto-balanced detection and the second harmonics detection method, adopting the open path multi-pass Herrriot cell to detect the concentration of CO in the combustion of alcohol blowtorch is accurate and contents the detection requirement. It was proved that the system made for measuring the concentration of CO in the flame of alcohol blowtorch in combustion establishes foundation well for developing on-line combustion monitoring based on TDLAS.

摘要

本文采用可调谐二极管激光吸收光谱技术(TDLAS),结合开路径多程赫里奥特池以及自平衡检测与波长调制技术相结合的新型检测方法,对酒精喷灯燃烧产生的一氧化碳浓度进行了测量。测量结果发现,酒精喷灯火焰中一氧化碳浓度的变化在燃烧过程中呈现出一定的周期性,一氧化碳的平均浓度经计算为49.4(体积比为10⁻⁶)。实验表明,自平衡检测与二次谐波检测方法相结合,采用开路径多程赫里奥特池检测酒精喷灯燃烧中的一氧化碳浓度是准确的,满足检测要求。证明了所搭建的用于测量酒精喷灯燃烧火焰中一氧化碳浓度的系统,为基于TDLAS的在线燃烧监测开发奠定了良好基础。

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