Zhang Ju-Cheng, Liu Wei, Yi Zhong-Zhou, Qiu Cheng-Shu, Li Ying, Yan He-Ping
Key Laboratory of Natural Pharmaceutical & Chemical Biology of Yunnan Province, School of Science, Honghe University, Mengzi 661100, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Nov;28(11):2699-702.
In the present paper, the authors prepared all the samples by the same method, and optimized the work conditions for flame qtomic absorption spectrometry. FAAS was applied to determine the trace elements, such as Pb, Cr, Cd, Cu, Zn, Hg, Se etc, in Elsholtzia bodineri Vaniot. from Mengzi, Shiping, Mile and Jianshui located in Honghe state. The method is simple, rapid and accurate, and allows simultaneous determination of many elements. The recoveries were in the range of 98.7%-116.4%, and RSD was 0.07%-1.69%. The contents of Pb, Cd and Hg were 53.47, 6.03 and 7.68 microg x g(-1), respectively, in the sample from Jianshui, and were higher than those from other areas. The content of Mn was the highest, and was higher in Mengzi than in other areas, and the average content in the four samples was 913.48 microg x g(-1), which was higher than the content in the soil. Fe is the semi-microelement whose average content in Elsholtzia bodineri Vaniot. from Honghe was 688.46 microg x g(-1), the high-to-low content sequence of Fe in terms of location was Mengzi, Mile, Shiping and Jianshui. The average content of Zn was 116.64 microg x g(-1), and the highest one was from Shiping. But we did not obtain the data of Se in the Elsholtzia bodineri Vaniot. from Honghe state by AAS, and did not detect Hg in samples from Shiping and Mile. The content of the detected elements in Mengzi's sample had the sequence as follows; Mn > Fe > Zn > Pb > Cu > Cr > Cd > Hg>Se, while the sequence was Mn > Fe > Zn > Pb > Cu > Hg > Cd > Cr > Se in the sample of Jianshui, Mn > Fe > Z n >Pb > Cu > Cd > Cr > Hg > Se in Shiping, and Fe > Mn > Zn > Pb > Cu > Cd > Cr > Hg > Se in Mile. The results show that the content of the trace elements is high, especially, Mn, Fe and Zn, in Elsholtzia bodineri Vaniot. in Honghe. Therefore, Elsholtzia bodineri Vaniot., which can be used as drug or beverage, is worth exploitation.
在本论文中,作者采用相同方法制备了所有样品,并优化了火焰原子吸收光谱法的工作条件。应用火焰原子吸收光谱法测定了来自红河州蒙自、石屏、弥勒和建水的鸡脚香中铅、铬、镉、铜、锌、汞、硒等微量元素。该方法简便、快速、准确,可同时测定多种元素。回收率在98.7% - 116.4%之间,相对标准偏差为0.07% - 1.69%。建水样品中铅、镉和汞的含量分别为53.47、6.03和7.68μg·g⁻¹,高于其他地区。锰含量最高,蒙自的锰含量高于其他地区,四个样品中的平均含量为913.48μg·g⁻¹,高于土壤中的含量。铁是微量元素,红河鸡脚香中铁的平均含量为688.46μg·g⁻¹,按产地铁含量从高到低的顺序为蒙自、弥勒、石屏和建水。锌的平均含量为116.64μg·g⁻¹,石屏的锌含量最高。但我们未通过原子吸收光谱法获得红河州鸡脚香中硒的数据,且在石屏和弥勒的样品中未检测到汞。蒙自样品中所测元素含量顺序为:锰>铁>锌>铅>铜>铬>镉>汞>硒,建水样品中顺序为:锰>铁>锌>铅>铜>汞>镉>铬>硒,石屏样品中顺序为:锰>铁>锌>铅>铜>镉>铬>汞>硒,弥勒样品中顺序为:铁>锰>锌>铅>铜>镉>铬>汞>硒。结果表明,红河鸡脚香中微量元素含量较高,尤其是锰、铁和锌。因此,可作为药材或饮品的鸡脚香值得开发利用。