Luminescent heteropolynuclear complexes of 3,5-dimethylpyrazolate [Pt2Au2M2(Me2pz)8] (M = Ag, Cu) showing the synergistic effect of three transition elements in the excited state.

作者信息

Umakoshi Keisuke, Saito Keizo, Arikawa Yasuhiro, Onishi Masayoshi, Ishizaka Shoji, Kitamura Noboru, Nakao Yoshihide, Sakaki Shigeyoshi

机构信息

Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, Bunkyo-machi, Nagasaki 852-8521, Japan.

出版信息

Chemistry. 2009;15(17):4238-42. doi: 10.1002/chem.200900290.

Swap the coins! The Pt(2)Au(2), Pt(2)Au(2)Cu(2), and Pt(2)Au(2)Ag(2) complexes of 3,5-dimethylpyrazolate exhibit yellow-green, orange, and sky-blue luminescence, respectively (see figure). The emission energies of Pt(2)Au(2)M(2) complexes can be controlled by the change of the third coinage metal ions M. The Pt(2)Au(2)M(2) complexes take the cis configuration with respect to the Au(2)M(2) plane.